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There are 4 fourteen-letter words beginning with SULPHA

SULPHACETAMIDE	• sulphacetamide n. Alternative form of sulfacetamide. • SULPHACETAMIDE n. a sulphonamide used in eye drops against conjunctivitis, etc., also SULFACETAMIDE.
SULPHADIAZINES	• sulphadiazines n. Plural of sulphadiazine. • SULPHADIAZINE n. a sulphonamide used, usually in combination with an antibiotic, in the treatment of pneumonia, meningitis, etc.
SULPHANILAMIDE	• sulphanilamide n. (British spelling, pharmacology) The amide of sulphanilic acid, used to treat streptococcal infections;… • SULPHANILAMIDE n. a white crystalline compound formerly used as an antibacterial drug.
SULPHATHIAZOLE	• sulphathiazole n. Alternative spelling of sulfathiazole. • SULPHATHIAZOLE n. a sulphonamide formerly used in human medicine against staphylococcal infection (now only used in veterinary medicine), also SULFATHIAZOLE.

Scrabble words — in black are valid world wide — in RED are not valid in North America — in GREEN are valid only in North America.
Definitions are short excerpt from the WikWik.org and 1Word.ws.

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English Wiktionary: 14 words
Scrabble in French: no word
Scrabble in Spanish: no word
Scrabble in Italian: no word
Scrabble in German: no word
Scrabble in Romanian: no word

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